Chlorinated hydrocarbons and hatching success in Baltic herring spring spawners

Eggs from 69 females of spring spawning herring from the German Baltic coast (Travemünde, April 1979) were incubated in clean sea water (20‰ S, temperature 8°C) under standard conditions. Sixty-one trials could be used for the evaluation of hatching success. Viable hatch was taken as a measure to evaluate the effects of chlorinated hydrocarbons accumulated in gonads, liver and muscle of parental fish.PCB levels in running ripe females ranged on a wet weight basis between 19 and 241 ng g^?1 (gonad), 20 and 377 ng g^?1 (liver) and 11 and 1820 ng g^?1 (muscle). Concentrations of other chlorinated hydrocarbons (DDD, DDE, γ-HCH, etc.) were in the same range as reported by other authors for Baltic herring (Huschenbeth, 1973, 1977). Viable hatch was significantly affected at ovary DDE concentrations higher than 18 ng g^?1 (wet wt) and PCB concentrations of more than 120 ng g^?1 (wet wt).Results are compared with data obtained during earlier investigations with flounder eggs.     

Provenance of the Bosnian Flysch

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.     

Coupling an ocean wave model to an atmospheric general circulation model

A coupled model, consisting of an ocean wave model and an atmospheric general circulation model (AGCM), is integrated under permanent July conditions. The wave model is forced by the AGCM wind stress, whereas the wind waves modify the AGCM surface fluxes of momentum, sensible and latent heat. We investigate the following aspects of the coupled model: how realistic are the wave fields, how strong is the coupling, and how sensitive is the atmospheric circulation to the spatially and temporally varying wave field. The wave climatology of the coupled model compares favorably with observational data. The interaction between the two models is largest (although weak) in the storm track in the Southern Hemisphere. Young windsea, which is associated with enhanced surface fluxes is generated mostly in the equatorward frontal area of an individual cyclone. However, the enhancement of the surface fluxes is too small to significantly modify the climatological mean atmospheric circulation.This paper was presented at the Second International Conference on Modelling of Global Climate Variability, held in Hamburg 7–11 September 1992 under the auspices of the Max Planck Institute for Meteorology. Guest Editor for these papers is L. Dümenil     

Nd-, Sr-, O-isotopic and chemical evidence for a two-stage contamination history of mantle magma in the Central-Alpine Bergell intrusion

Two different contamination processes have been identified as having been operative in the genesis of a plutonic suite: initial contamination of a mantle source, and subsequent crustal contamination of uprising partial melts from the mantle. These processes are indicated by a detailed analyses of Nd, Sr, and oxygen isotopes together with major-and trace-elements of the 32–30 Ma calc-alkaline Bergell intrusion. This intrusion is located at the suture of the Alpine continental collision zone and contains rock types capable of discriminating between mantle and intracrustal processes. A range from basaltic-andesitic dykes in the surrounding country rocks, cumulitic hornblendites, gabbros, tonalite, granodiorite and lamprophyres, to pegmatites and aplites, is exposed in this single intrusion. The results of REE modelling and isotopic compositions of the basic members suggest that the cumulates were fractionated from a picrobasaltic liquid originating by partial melting of enriched subcontinental mantle (_Nd=+4). Increases in ⁸⁷Sr/⁸⁶Sr (0.7055) and ¹⁸O(+6.7) in these samples relative to the mantle array and compositions of other Periadriatic intrusions are most likely the result of an initial contamination of the mantle source by dehydration or partial melting of altered subducted oceanic crust. Slight differentiation of such a picrobasaltic liquid produced the basaltic-andesitic dykes. Simultaneous fractional crystallization and contamination of the uprising magma by continental crust produced crustal isotopic signatures which increase with acidity to values of (_Nd=-7.6), ⁸⁷Sr/⁸⁶Sr=0.716 and ¹⁸O=+10. The crustal imprint and LREE enrichment in the dominating tonalite increase with decreasing crystallization depth which indicates that the tonalites were emplaced in several distinct batches with different degrees of contamination. Shoshonitic lamprophyres, which intruded into the partly solidified granodiorite, were generated in a deep, strongly contaminated mantle source. The posttectonic 26 Ma Novate leucogranite is not cogenetic with the main Bergell body, but rather formed from a predominantly crustal source. If the described features are indeed due to mantle source contamination processes, which are well known for volcanic arcs, it must be concluded that these may also play a significant role in the genesis of calcalkaline plutonic suites.     

Structural and metamorphic evolution of the Sierras Australes (Buenos Aires Province/Argentina)

The Precambrian Basement Complex rocks as well as the Early to Late Palaeozoic cover sediments of the Sierras Australes were affected by one dominant folding and shearing event verging northeastward during Middle to Late Permian times. Strain estimates point to a minimal flattening and lateral shortening of the sedimentary cover sequence of c.20% and c.24% respectively. Continuing rotational deformation within first and second shear and thrust zones is documented by second and third folding and shearing. To the SW the fold belt changes into a fold and thrust belt where imbrication involves the basement. The deformational events were accompanied and outlasted by anchizonal to greenschist facies metamorphism proven by illite crystallinity and quartz deformation and recrystallization data. A temperature increase from ENE to WSW and also from N to S allowed a more ductile deformation of the rock sequence due to different deformation mechanisms operating. The folding and thrusting events were followed by strike-slip shearing on subvertical shear planes and shear zones under an overall sinistral transpressive regime. A model for the tectonic evolution of the Sierras Australes is proposed and some implications for its setting in the Gondwana reconstruction are given.

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Zusammenfassung Das präkambrische Basement sowie die alt- und jungpaläozoischen Deckschichten der Sierras Australes wurden während des Mittl. bis Ob. Perm von einer NE vergenten Faltung und Scherung erfaßt. Strain-Abschätzungen deuten auf eine minimale Plättung und laterale Verkürzung der Sedimentfolge von ca. 20% bzw. 24%. Die fortlaufende relationale Deformation in den ersten und zweiten Scher- und Überschiebungszonen ist durch zweite und dritte Faltung mit Scherung dokumentiert. Der Sierras Australes-Faltengürtel geht nach SW in einen Falten-Überschiebungsgürtel über, dessen nach NE gerichtete Imbrikationen das Basement einbeziehen. Daten der Illit-Kristallinität und Quarz-Deformation/-Rekristallisation zeigen, daß die Deformationen von anchizonaler bis seicht-grünschieferfazieller Metamorphose begleitet und überdauert wurden. Mit der von ENE nach WSW bzw. N nach S zunehmenden Temperierung setzten verschiedene Deformationsmechanismen ein. Sie ermöglichten eine zunehmend duktile Verformung der Gesteinsfolgen. Auf die Faltungen und Auf-/Überschiebungen folgten Lateralverschiebungen an subvertikalen Scherflächen und -zonen unter einem sinistralen transpressiven Regime. Für die tektonische Entwicklung der Sierras Australes wird ein Modell vorgeschlagen, und die Folgerungen für die Stellung in der Gondwana-Rekonstruktion werden angeführt.

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Résumé Les roches du socle précambrien ainsi que la couverture sédimentaire éo- à tardi-paléozoïque des Sierras Australes ont été affectées, au cours du Permien moyen à supérieur, d'un plissement et d'un cisaillement à vergence nord-est. Les déformations sont estimées à au moins 20% d'aplatissement et 24% de raccourcissement latéral. Dans la première et la deuxième zone de cisaillement et de charriage, la déformation rotationnelle continue s'exprime par les deuxième et troisième plissements. Vers le SW la ceinture plissée passe à une ceinture plissée et charriée qui comporte des imbrications du socle. Les déformations ont été accompagnées et suivies d'un métamorphisme de faciès d'anchizone à «schistes verts», ainsi qu'en attestent la cristallinité de l'illite et la déformation et recristallisation du quartz. L'accroissement de la température de l'ENE vers l'WSW ainsi que du N vers le S a donné lieu à des mécanismes de déformation de caractère de plus en plus ductile. La phase de plissement et de charriage a été suivie par un régime de cisaillements décrochants sénestres le long de plans et de shear-zones subverticaux. Les auteurs proposent un modèle de l'évolution tectonique des Sierras Australes et discutent de son insertion dans la reconstruction du Gondwana.

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NE , . 20 24%. . , , , . : , - . ENE WSW N S, . . . .

     

Phosphorus retention in calcareous soils and the effect of organic matter on its mobility

A survey of the interactions between phosphorus (P) species and the components of calcareous soils shows that both surface reactions and precipitation take place, especially in the presence of calcite and limestone. The principal products of these reactions are dicalcium phosphate and octacalcium phosphate, which may interconvert after formation. The role of calcium carbonate in P retention by calcareous soils is, however, significant only at relatively high P concentrations – non-carbonate clays play a more important part at lower concentrations. In the presence of iron oxide particles, occlusion of P frequently occurs in these bodies, especially with forms of the element that are pedogenic in origin. Progressive mineralization and immobilization, often biological in nature, are generally observed when P is added as a fertilizer.     

Understanding Perturbation on the Simplex: A Simple Method to Better Visualize and Interpret Compositional Data in Ternary Diagrams

Perturbation is an operation defined on the simplex and can be used for centering compositional data in a ternary diagram, applying objective criteria. Because a straight line in the original diagram is still astraight line in the perturbed diagram, gridlines or compositional fields defined by straight lines can easily be included in the operation. Simultaneous perturbation of data, gridlines, and/or compositional fields is shown to improve both visualization and graphical interpretation of compositions in ternary diagrams. This is illustrated by some examples using simulated as well as real data.     

Anhydrite-bearing rocks from the Rožná district (Moldanubian zone,Czech Republic): high-grade metamorphosed exhalites?

Several types of anhydrite-bearing rocks have been found in the amphibolite-facies metamorphosed rocks at the north-eastern margin of the Moldanubian Zone. Anhydrite either forms monomineralic bands up to 40 cm thick, or occurs in the form of disseminated grains in surrounding calc-silicate gneiss together with feldspar, scapolite, amphibole, pyroxene, epidote and pyrite. The isotopic composition of sulphur ('³⁴S=30.6 to 32.3‰) and strontium (⁸⁷Sr/⁸⁶Sr=0.70797 to 0.70781) in anhydrite may indicate a marine source of sulphate. The isotopic ratio of strontium is in the same range as that of metamorphosed strata-bound barite-sulphide ores, which have been previously described in the same area. The '³⁴S values of coexisting pyrite range from 21.4 to 22.5‰, the (³⁴S_{anhydrite-pyrite} corresponding to the metamorphic temperature of 600 to 660 °C. In contrast to many submarine-exhalative deposits, the oxygen isotopic compositions of anhydrite ('¹⁸O=9.3 to 10.2‰) are lighter than that of barite ('¹⁸O=10.4 to 13.8‰). This indicates that the both minerals are not in isotopic equilibrium. Therefore, it is probable that anhydrite and barite from the Ro—ná district were deposited from fluids that contained different proportions of seawater and hydrothermal fluids or from hydrothermal fluids that underwent variable extent of oxygen isotope exchange with seafloor rocks. The '¹³C values in calcite ('¹³C=-17.2 to -18.7‰) from anhydrite-bearing rock are lower than those in distant marbles. As graphite is absent in anhydrite- and calcite-bearing rocks, impoverishment in the ¹³C isotope cannot be attributed to the graphite-carbonate isotopic exchange during metamorphism. It is proposed that low '¹³C values in carbonates are caused by pre-metamorphic oxidation of organic matter in course of hydrothermal processes. Anhydrite and anhydrite-bearing calc-silicate gneiss from the north-eastern part of the Moldanubian Zone are interpreted to be the high-grade metamorphosed analogue of anhydrite-rich exhalites commonly found in submarine-exhalative hydrothermal deposits.     

Management and development of river basins in north bengal using remote sensing techniques

River basin management and development are most important for utilising and conserving the water resources in any region where the average annual rainfall is highly fluctuating, the North Bengal is one of such region. Though there are a large number of rivers having a large catchment area in the hills and carry a huge amount of water during rainy season but they are completely dry in winter and summer. The upper part of majority of river basins arc highly sensitive to water erosion and land slides due to deforestation, intensive cultivation, increased settlements in sloping and erosion prone areas. So, floods in the rainy season and droughts in summer months are frequent features in North Bengal. In view of this proper management and effective conservation of land and water resources is necessary to develop the region. An integrated river basin management consisting soil conservation, afforestation, flood control, and adoption of suitable cropping pattern is essential for economic development of North Bengal.